There is great Coffee and friendly service at a new Cafe on 206 Somerville Rd. Called project 206 Cafe & Espresso bar. They do Segafredo coffee and they have Yummy meals, a relaxing Courtyard out the back! They also do heaps of take away options as well.
Many great coffee spots in Yarraville! I agree with @happymaree, the new shop there is FANTASTIC! other favourite haunts are the Cornershop, Hausfrau and Alfa Bakehous! all shops offer a wide range of lovely blends and a lot of other quality items too! :)
There's a new lil place at 229 Somerville Rd, about 1km west of the station called happymaree that's an art studio and shop but are also doing GREAT coffee, Four Rascals 'Rapscallion' blend. I will admit I'm the Barista :) but all the feedback has been great! If it's too far to walk try Wee Jeanie (spelling?) ipon Anderson St in the village. Hausfrau is also good :)